There is no injury concern for Ederson but the Manchester City goalkeeper was not named among Tite's three goalkeepers.
Another surprise omission was veteran full-back Dani Alves, who was seemingly left out at the expense of 19-year-old Gabriel Menino.
Selecao take on Bolivia on October 9 before they travel to Peru four days later as they begin their journey to the 2022 World Cup in Qatar.
Goalkeepers: Alisson (Liverpool), Santos (Athletico), Weverton (Palmeiras).
Defenders: Danilo (Juventus), Gabriel Menino (Palmeiras), Alex Telles (Porto), Felipe (Atletico Madrid), Renan Lodi (Atletico Madrid), Marquinhos (Paris Saint-Germain), Thiago Silva (Chelsea), Rodrigo Caio (Flamengo).
Midfielders: Casemiro (Real Madrid), Fabinho (Liverpool), Philippe Coutinho (FC Barcelona), Bruno Guimaraes (Olympique Lyon), Douglas Luiz (Aston Villa), Everton Ribeiro (Flamengo).
Forwards: Roberto Firmino (Liverpool), Gabriel Jesus (Manchester City), Richarlison (Everton) Rodrygo (Real Madrid), Everton (Benfica), Neymar (Paris Saint-Germain).